4.8 Article

Experimental evidence for hydrogen incorporation into Earth's core

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NATURE COMMUNICATIONS
卷 12, 期 1, 页码 -

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NATURE RESEARCH
DOI: 10.1038/s41467-021-22035-0

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  1. JSPS Kakenhi
  2. Imaging Platform program by MEXT

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This experimental study shows that hydrogen exhibits a strong siderophile behavior under conditions of core formation, and may explain a significant portion of the density deficit and sound velocity excess of the Earth's outer core compared to pure iron. Additionally, hydrogen could be an important constituent in the metallic cores of terrestrial planets or moons with a mass exceeding approximately 10% of the Earth.
Hydrogen is one of the possible alloying elements in the Earth's core, but its siderophile (iron-loving) nature is debated. Here we experimentally examined the partitioning of hydrogen between molten iron and silicate melt at 30-60 gigapascals and 3100-4600 kelvin. We find that hydrogen has a metal/silicate partition coefficient D-H >= 29 and is therefore strongly siderophile at conditions of core formation. Unless water was delivered only in the final stage of accretion, core formation scenarios suggest that 0.3-0.6 wt% H was incorporated into the core, leaving a relatively small residual H2O concentration in silicates. This amount of H explains 30-60% of the density deficit and sound velocity excess of the outer core relative to pure iron. Our results also suggest that hydrogen may be an important constituent in the metallic cores of any terrestrial planet or moon having a mass in excess of similar to 10% of the Earth.

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