No more waste at the elemental analysis of airborne particulate matter on quartz fibre filters

Particulate matter (PM) is the major environmental pollutant. Its elemental composition is routinely monitored. Inductively coupled plasma mass spectroscopy (ICPMS) is commonly applied after a PM sample has been digested by an acid during a microwave treatment. In this case, sample preparation procedure is laborious, sometimes incomplete and produces toxic waste. In this paper we show that direct sample introduction to ICPMS by laser ablation (LA-ICPMS) is of huge advantage. Minimal quantity of a sample is required for the analysis (<1 cm(2)) and no chemical waste is produced. The study focused on the most universal and widely used quartz fibre filter samples and we show that LA-ICPMS can be successfully applied for the determination of the elemental composition of such samples. Some effort is, however, still needed to develop an autosampler for the LA-ICPMS system and to provide commercial matrix-matched standards for this application to be implemented in environment laboratories worldwide.

Automated summary

This study demonstrates that direct sample introduction to ICPMS by laser ablation (LA-ICPMS) provides significant advantages in terms of simplifying sample preparation procedures and avoiding the generation of chemical waste. The research shows that LA-ICPMS can successfully be applied for the determination of the elemental composition of quartz fibre filter samples.