期刊
SUPRAMOLECULAR CHEMISTRY
卷 33, 期 4, 页码 97-106出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2021.1917768
关键词
Quinoxaline cavitands; cavity partial rigidification; X-ray crystal structure; upper rim bridging
资金
- Ministero dell'Istruzione, dell'Universita e della Ricerca [20179BJNA2]
The unique temperature, solvent and pH driven vase to kite equilibrium in quinoxaline cavitands allows reversible uptake and release of guests, but the associated cavity breathing reduces complexation strength. This study reports the synthesis and structural characterization of quinoxaline-based cavitand baskets, suggesting potential solutions for cavity rigidification.
The unique temperature, solvent and pH drivenvase to kite equilibrium in quinoxaline cavitands allows the reversible uptake and release of guests. However, the cavity breathing associated with this conformational switch reduces the strength of complexation. A limited number of solutions have been proposed for the cavity rigidification, using either H-bonding, metal coordination or covalent connections. Here we report the synthesis and structural characterisation of quinoxaline-based cavitand baskets, which present two distal quinoxaline walls linked together. Baskets A and B were obtained through a bridging reaction starting from an AC di-quinoxaline bridged cavitand using two different di-quinoxaline moieties. In both cases, two isomers were obtained: isomer C-2, with the linking unit crossing the cavity mouth, and isomer C-s, having the linker sideways. The isomers were identified through H-1 NMR analysis. In the case of basket A-C-s, the resolved molecular structure confirmed the C-s symmetry of the basket. [GRAPHICS] .
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