期刊
SMALL
卷 17, 期 22, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202005686
关键词
confinement effect; covalent organic frameworks; crystalline porous materials; heterogeneous asymmetric catalysis; metal– organic frameworks
类别
资金
- National Natural Science Foundation of China [21203102]
- NCC Fund [NCC2020PY02]
- Tianjin Municipal Natural Science Foundation [17JCYBJC22600]
- MOE [IRT13R30]
- Fundamental Research Funds for the Central Universities
Asymmetric catalysis is essential due to the increasing demand for optically pure substances. Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) show great potential for heterogeneous asymmetric catalysis. The unique properties of MOFs and COFs make them highly active and enantioselective for a wide range of asymmetric catalytic organic transformations.
Asymmetric catalysis is of crucial importance owing to the huge and rising demand for optically pure substances. Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), as two emerging crystalline porous materials, have presented great promising applications for heterogeneous asymmetric catalysis. The unique properties, such as, highly regular porous structures, prominent structural tunability, and well-ordered catalytic sites, render chiral MOFs (CMOFs) and chiral COFs (CCOFs) highly active and enantioselective for a large number of asymmetric catalytic organic transformations. Furthermore, they provide a useful platform for facile mechanistic understanding and catalyst design. This review provides an overview of the advancements in CMOFs and CCOFs for asymmetric catalysis. The designs, syntheses and structures of these crystalline porous materials, and their asymmetric catalytic performance are described. And the perspectives on challenges and opportunities in development of CMOFs and CCOFs are discussed. It is anticipated that this review will shed light on the heterogeneous asymmetric catalysis with CMOFs and CCOFs and motivate further research in this promising field.
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