期刊
SMALL
卷 17, 期 48, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202006821
关键词
3D graphene; carbon nanotubes; electrochemical capacitors; transition metal‐ dichalcogenides
类别
资金
- OPUS project - National Science Centre, Poland [2018/31/B/ST4/01852]
The physicochemical and electrochemical properties of carbon composites with two sulfides ReS2 and FeS2 are studied, showing potential applications for electrochemical capacitors. The structure-to-capacitance correlation for composites with various TMDs loading is emphasized, with ReS2 composite having lower capacitor voltage due to quicker electrolyte decomposition, while FeS2 composite can operate at extended voltage limits.
Transition metal dichalcogenides (TMDs) are emerging low-dimensional materials with potential applications for electrochemical capacitors (EC). Here, physicochemical and electrochemical characterizations of carbon composites with two sulfides ReS2 and FeS2 are reported. To enhance conductivity, multiwalled carbon nanotubes (NTs) serve as a support for ReS2 while 3D graphene-like network (3DG) is utilized for FeS2 deposition. Unique structure of carbon/TMDs composites allows a faradaic contribution of sulfides to be exploited. Capacitance values, charge/discharge efficiency, capacitance retention, charge propagation, cyclabilty, and voltage limits of EC with carbon/sulfide composites in aqueous neutral solutions (Li2SO4, Na2SO4) are analyzed. Special attention is devoted to energetic efficiency of capacitive charge/discharge processes. Structure-to-capacitance correlation for the composites with various TMDs loading is thoroughly emphasized. The more defected structure of layered NTs/ReS2 composite is responsible for the lower capacitor voltage (0.8 V) owing to quicker electrolyte decomposition. Additionally, the catalytic effect of Re for hydrogen evolution reaction plays a crucial role in EC voltage restriction. Contrary, the operating voltage of capacitor based on 3DG/FeS2 is able to be extended until 1.5 V in sodium sulfate electrolytic solution.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据