期刊
SMALL
卷 17, 期 18, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202005605
关键词
electrocatalyst; lithium‐ ion battery; oxygen evolution reaction; phase transition
类别
资金
- NRF (National Honor Scientist Program) [2010-0020414]
- 2021 Research Fund of UNIST [1.210033.01]
- National Research Foundation of Korea - Ministry of Science and ICT [NRF-2019R1C1C1009324]
- National Research Foundation of Korea [미래선도형 특성화연구(2021), 2019R1C1C1009324, 2010-0020414] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The study demonstrates that Na/Al codoped Li-Ru-Ni-O layered electrodes can serve as an efficient bifunctional electrocatalyst for both lithium-ion battery and oxygen evolution reaction. The doping process improves Li diffusion, stabilizes the layered structure, and provides abundant active sites for accelerating OER reactions.
The rational design of bifunctional electrocatalyst through simple synthesis with high activity remains a challenging task. Herein, Na/Al codoped Li-excess Li-Ru-Ni-O layered electrodes are demonstrated with defects/dislocations as an efficient bifunctional electrocatalyst toward lithium-ion battery (LIB) and oxygen evolution reaction (OER). Toward LIB cathode, specific capacity of 173 mAh g(-1) (0.2C-rate), cyclability (>95.0%), high Columbic efficiency (99.2%), and energy efficiency (90.7%) are achieved. The codoped electrocatalyst has exhibited OER activity at a low onset potential (270 mV@10 mA cm(-2)), with a Tafel slope 69.3 mV dec(-1), and long-term stability over 36 h superior to the undoped and many other OER electrocatalysts including the benchmark IrO2. The concurrent doping resides in the crystal lattice (where Na shows the pillaring effect to improve facile Li diffusion), Al improves the stabilization of the layered structure, and defective structures provide abundant active sites to accelerate OER reactions.
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