4.8 Article

Ion-capture electrodialysis using multifunctional adsorptive membranes

期刊

SCIENCE
卷 372, 期 6539, 页码 296-+

出版社

AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.abf5991

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资金

  1. US Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences [DE-SC0001015]
  2. US DOE, Office of Science, Office of Basic Energy Sciences [DE-SC0019992]
  3. Laboratory Directed Research and Development (LDRD) Program of the US DOE [DE-AC02-05CH11231]
  4. US National Science Foundation
  5. Center for Integrated Nanotechnologies, an Office of Science User Facility
  6. US DOE's National Nuclear Security Administration [DE-NA-0003525]
  7. Center for Gas Separations, an Energy Frontier Research Center
  8. Molecular Foundry

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The study introduces a novel adsorptive membrane technology for efficient purification of water sources and removal of toxic contaminants with a one-step separation process. The technology features robust, selective, and tunable characteristics, making it applicable for multifunctional separations.
Technologies that can efficiently purify nontraditional water sources are needed to meet rising global demand for clean water. Water treatment plants typically require a series of costly separation units to achieve desalination and the removal of toxic trace contaminants such as heavy metals and boron. We report a series of robust, selective, and tunable adsorptive membranes that feature porous aromatic framework nanoparticles embedded within ion exchange polymers and demonstrate their use in an efficient, one-step separation strategy termed ion-capture electrodialysis. This process uses electrodialysis configurations with adsorptive membranes to simultaneously desalinate complex water sources and capture diverse target solutes with negligible capture of competing ions. Our methods are applicable to the development of efficient and selective multifunctional separations that use adsorptive membranes.

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