期刊
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
卷 91, 期 3, 页码 393-400出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363221030099
关键词
platinum complexes; nitriles; isocyanides; luminescence
资金
- Council for Science at the President of the Russian Federation [MK-1476.2019.3]
A series of novel platinum(II) complexes with nitrile and isocyanide ligands were synthesized and their structures and crystal packing were studied using various analytical methods. The photophysical properties of the synthesized complexes were also investigated.
A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60-80% yields from the dimer [{Pt(ppy)Cl}(2)] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据