期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2016, 期 18, 页码 3060-3064出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201600515
关键词
Homogeneous catalysis; Ruthenium; Hydrogenation; Reduction; Amination; Aldehydes
资金
- University of Kaiserslautern, Research College MAGNENZ
- State Research Unit (NanoKat), Germany
The ruthenium complex [((6)-cymene)Ru(Cl)(dpmpy)](+) {dpmpy = 2-[2-(dimethylamino)pyrimidin-4-yl]pyridine} is highly reactive in catalyzing the reductive amination of aromatic aldehydes through in situ generated imines with 2-propanol as the hydrogen source following a transfer-hydrogenation mechanism. This transformation does not require any activating additives and is applicable to a broad variety of aldehydes.
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