期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2016, 期 31, 页码 5220-5226出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201601011
关键词
Cycloaddition; Dienes; Ketones; Organocatalysis; Spiro compounds
资金
- Department of Science and Technology (DST), Science and Engineering Research Board, New Delhi [EMR/2015/000860]
- Council of Scientific and Industrial Research (CSIR), New Delhi
- University Grants Commission (UGC), Networking Centre, School of Chemistry, UoH
Herein, we present the Bronsted-acid-controlled, primary-amine-catalyzed stereoselective asymmetric synthesis of druglike six-membered spirooxindoles from simple aliphatic substrates through a Barbas [4+2]-cycloaddition reaction by using 2-aminobuta-1,3-diene catalysis under ambient conditions.
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