期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2016, 期 5, 页码 913-917出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201501614
关键词
Ionic liquids; Lithium; Solvates; Lewis acids; Acceptor number
资金
- Institute for Frontier Materials (IFM)
- Strategic Research Centre (SRC) for Chemistry and Biotechnology
- Facuilty of Science, Engineering, and Built Environment
- IFM
Solvate ionic liquids (SILs) consisting of lithium bis(trifluoromethylsulfonyl)imide dissolved in tri- or tetraglyme have recently emerged as a novel class of ionic liquids. Herein, the first use of solvate ionic liquids as a replacement for molecular solvents in electrocyclization reactions is reported. The SILs promoted both Diels-Alder and [2+2] cycloaddition reactions, compared to an appropriate molecular solvent, and 5 M lithium perchlorate in diethyl ether. The Gutmann acceptor number (AN) of these solvate ionic liquids has also been determined by P-31 NMR spectroscopy to be 26.5, thus being modest Lewis acids.
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