期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2016, 期 10, 页码 1908-1914出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201501616
关键词
Green chemistry; Cross-coupling; Amination; Palladium; Carbene ligands
资金
- Russian Foundation for Basic Research (RFBR) [13-03-1224013 ofi_m]
A highly efficient solvent-free protocol for the Buchwald-Hartwig (hetero)arylation of anilines, diarylamines, and dialkylamines mediated by the expanded-ring N-heterocyclic carbene palladium complex (THP-Dipp)Pd(cinn)Cl [THP-Dipp = 1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-yl-idene; cinn = cinnamyl, 3-phenylallyl] was developed. The catalytic protocol was efficient for the coupling of amines and (hetero)aryl chlorides and bromides bearing donor, acceptor, and bulky substituents.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据