期刊
POLYMER ENGINEERING AND SCIENCE
卷 61, 期 6, 页码 1662-1672出版社
WILEY
DOI: 10.1002/pen.25690
关键词
anionic polymerization; composites; molding; polyamides
资金
- Fundamental Research Funds for the Central Universities [2312017BHYC04A, XK1802-3]
- National Key Research and Development Program of China [2019YFC1906105, 2020YFB1506102]
This study investigated the influence of fiber dissolution on the properties and structure of Single-polymer composites (SPCs) by adjusting polymerization time with varying activator dosage. It was found that the highest activator dosage led to maximum tensile strength, while a lower dosage resulted in longer polymerization time, destruction of oriented chain structure, and formation of oligomers, resulting in low strength and high deformation in SPCs. To achieve a good reinforcing effect, creating a sufficiently large dissolution window by reducing polymerization time is necessary.
Single-polymer composites (SPCs) are promising composite materials in which the reinforcement and matrix have the same chemical composition. In situ polymerization shows a broad application potential for producing SPCs due to its wide temperature window. However, the dissolution of fiber reinforcements in the liquid monomer destroys the oriented chain structure of the fibers and affects the properties of SPCs. In this study, the polymerization time was adjusted by varying the activator dosage. The influence of the dissolution of fibers on the properties and the structure of SPCs was investigated. The maximum tensile strength was achieved at the highest activator dosage. A longer duration was required for the polymerization due to the low-activator dosage, which led to the destruction of the oriented chain structure and the formation of a large amount of oligomers on account of the dissolution. Eventually, SPCs showed a low strength and a high deformation at break. In order to realize a good reinforcing effect, a sufficiently large dissolution window must be created by reducing the polymerization time. This study enhanced our understanding of the structure-property relationships of SPCs and provided a way to improve their mechanical characteristics.
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