期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2016, 期 22, 页码 3737-3747出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201600407
关键词
Synthetic methods; Semiconductors; Organic electronics; Optoelectronics; Thin films; Polymerization
资金
- National Program on Key Basic Research Project(973 Program) [2015CB351901]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09020201]
- National Natural Science Foundation of China (NSFC) [21402233]
- Natural Science Foundation of Jiangsu Province [BK2012631, BK20140387]
- Major Research plan of the National Natural Science Foundation of China [91123034]
- National Science and Technology Ministry [2012BAF13B05-402]
- Youth Innovation Promotion Association CAS [2013206]
- Open Fund of the State Key Laboratory of Luminescent Materials and Devices (South China University of Technology) [2012-skllmd-05]
A series of cross-linkable bipolar host materials containing carbazole (donor, D) and 1,2,4-triazole (acceptor, A) were designed and synthesized. The host materials with styryl groups can be thermally cross-linked by curing at 172-190 degrees C without any polymerization initiator. Excellent solvent resistance was observed for all the host materials, which is beneficial for the preparation of subsequent functional layers by solution processes. The highest occupied molecular orbital energy levels of 5.55, 5.58 and 5.54 eV are estimated for these host materials, which indicates low injection barrier from the hole transport layer. A current efficiency of 15.3 cd A(-1) and an external quantum efficiency of 4.6 % were achieved for solution-processed Ir(mppy)(3)-based OLEDs by using the cross-linkable host material.
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