期刊
ORGANOMETALLICS
卷 40, 期 9, 页码 1190-1194出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.1c00071
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资金
- National Natural Science Foundation of China [21602249]
- Fundamental Research Funds for the Central Universities
- Research Funds of Renmin University of China [20XNLG20]
- Public Computing Cloud Platform, Renmin University of China
The mesoionic carbene-stabilized PS+ cation 6 has been synthesized and characterized by single-crystal X-ray diffraction analysis for the first time. Computational investigations reveal the multiple-bond character of the phosphorus-sulfur bond, and preliminary coordination investigation shows kappa 1 ligation with the S atom bonded to Cu(I).
The mesoionic carbene-stabilized PS+ cation 6 has been synthesized and first characterized by single-crystal X-ray diffraction analysis. Computational investigations reveal the typical multiple-bond character of the phosphorus-sulfur bond. A preliminary coordination investigation shows kappa 1 ligation with the S atom bonded to Cu(I).
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