期刊
ORGANIC LETTERS
卷 23, 期 10, 页码 4057-4061出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c01303
关键词
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资金
- National Natural Science Foundation of China [21971116]
- Open Project of Chinese Materia Medica First-Class Discipline of Nanjing University of Chinese Medicine [2020YLXK011]
The site-specific oxidation of (sp(3))C-C(sp(3)) and (sp(3))C-H bonds in aryl alkanes by NaNO2/HCl is chemical-oxidant-free and transition-metal-free, using water as the solvent under mild conditions. This makes it valuable and attractive to synthetic organic chemistry.
A site-specific oxidation of (sp(3))C-C(sp(3)) and (sp(3))C-H bonds in aryl alkanes by the use of NaNO2/HCl was explored. The method is chemical-oxidant-free, transition-metal-free, uses water as the solvent, and proceeds under mild conditions, making it valuable and attractive to synthetic organic chemistry.
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