期刊
ORGANIC LETTERS
卷 23, 期 8, 页码 2900-2903出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c00537
关键词
-
资金
- National Natural Science Foundation of China [21922109, 21831007]
The recyclable organic photoreductant CBZ6 catalyzes the reductive coupling of aldehydes, ketones, and imines under purple light irradiation, producing 1,2-diols and 1,2-diamines. With a high oxidation potential, CBZ6 is suitable for the reductive coupling of carbonyl compounds and their derivatives, making it a promising candidate for large-scale photoreductive synthesis.
A recyclable organic photoreductant (1 mol % CBZ6)-catalyzed reductive (pinacol) coupling of aldehydes, ketones, and imines has been developed. Irradiated by purple light (407 nm) using triethylamine as an electron donor, a variety of 1,2-diols and 1,2-diamines could be prepared. The oxidation potential of the excited state of CBZ6 is established as -1.92 V (vs saturated calomel electrode (SCE)). The relative high reductive potential enables the reductive coupling of carbonyl compounds and their derivatives. CBZ6 can be prepared in gram scale and is acid/base- or air-stable. It could be applied in large-scale photoreductive synthesis and recovered in high yield after the reaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据