4.6 Article

Solution-processed pure Cu2ZnSnS4/CdS thin film solar cell with 7.5% efficiency

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Investigation of Zn/Sn ratio for improving the material quality of CZTS thin films with the reduction of Cu2-xS secondary phase

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Summary: A sputtering system was used to prepare high-quality Cu2ZnSnS4 (CZTS) thin films with controlled elemental ratios. Increasing sulfurization temperature led to elevated Cu/(Zn + Sn) and Zn/Sn ratios, resulting in enhanced Cu2-xS secondary phase formation and increased surface roughness and void density on the CZTS thin films. Lowering the sulfurization temperature with reduced Zn/Sn ratio demonstrated improved CZTS thin-film quality with increased XRD and Raman intensity, and reduced FWHM value.

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