4.8 Article

Joule-heated carbonized melamine sponge for high-speed absorption of viscous oil spills

期刊

NANO RESEARCH
卷 14, 期 8, 页码 2697-2702

出版社

TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-020-3274-y

关键词

joule-heat; melamine sponge; crude oil; viscosity; hydrophobic/oleophilic

资金

  1. National Natural Science Foundation of China [51732011, 21431006, 21761132008, 81788101, 11227901, 21805188]
  2. Foundation for Innovative Research Groups of the National Natural Science Foundation of China [21521001]
  3. Key Research Program of Frontier Sciences, CAS [QYZDJ-SSW-SLH036]
  4. National Basic Research Program of China [2014CB931800]
  5. Hefei Science Center of CAS [2015HSC-UE007]
  6. Anhui Initiative in Quantum Information Technologies [AHY050000]
  7. Fundamental Research Funds for the Central Universities [WK6030000077]

向作者/读者索取更多资源

Introducing heating function to oil sorbents enables fast cleanup of viscous crude oil spills in situ. Carbonized melamine-formaldehyde sponges (CMSs) exhibited superior heating performance and can be mass fabricated through a non-polluting pyrolysis process. The conductive CMSs can heat up quickly and significantly improve the efficiency and oil sorption capacity during oil spill remediation.
Introducing heating function to oil sorbents opens up a new pathway to the fast cleanup of viscous crude oil spills in situ. The oil sorption speed increases with the rise of the temperature, thus oil sorbents with high heating temperature are desirable. Besides, the oil sorbents also need to be produced environment-friendly. Here we present carbonized melamine-formaldehyde sponges (CMSs) that exhibited superior heating performance and the CMSs could be massively fabricated through a non-polluting pyrolysis process. The conductive CMSs could be heated over 300 degrees C with a low applied voltage of 6.9 V and keep above 250 degrees C for 30 min in the air without obvious damage. Such high heating performance enabled heating up the oil spills with a high rate of 2.65 degrees C.s(-1) and 14% improvement of oil sorption coefficient compared with the state-of-the-art value. We demonstrated that one joule-heated CMS could continuously and selectively collect viscous oil spills (9,010 mPa.s) 690 times its own weight in one hour. The CMSs will be a highly competitive sorbent material for the fast remediation of future crude oil spills.

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