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Conducting Silicone-Based Polymers and Their Application

期刊

MOLECULES
卷 26, 期 7, 页码 -

出版社

MDPI
DOI: 10.3390/molecules26072012

关键词

silicon-containing polymers; silane; silole; organic light-emitting diode (OLED); organic photovoltaic (OPV); sensors

资金

  1. Wroclaw University of Science and Technology [K20/8211104160]

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Conducting polymers have experienced rapid growth in both fundamental and applied research over the past two decades. Electrically conductive silicone polymers, a combination of inorganic elements and organic polymers, have emerged as the current state-of-the-art in optoelectronic materials. These materials exhibit excellent thermal stability and possess a range of unique properties such as low surface energy and biocompatibility.
Over the past two decades, both fundamental and applied research in conducting polymers have grown rapidly. Conducting polymers (CPs) are unique due to their ease of synthesis, environmental stability, and simple doping/dedoping chemistry. Electrically conductive silicone polymers are the current state-of-the-art for, e.g., optoelectronic materials. The combination of inorganic elements and organic polymers leads to a highly electrically conductive composite with improved thermal stability. Silicone-based materials have a set of extremely interesting properties, i.e., very low surface energy, excellent gas and moisture permeability, good heat stability, low-temperature flexibility, and biocompatibility. The most effective parameters constructing the physical properties of CPs are conjugation length, degree of crystallinity, and intra- and inter-chain interactions. Conducting polymers, owing to their ease of synthesis, remarkable environmental stability, and high conductivity in the doped form, have remained thoroughly studied due to their varied applications in fields like biological activity, drug release systems, rechargeable batteries, and sensors. For this reason, this review provides an overview of organosilicon polymers that have been reported over the past two decades.

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