4.2 Article

Nucleophilic addition of amino acid esters to nitrilium derivatives of closo-decaborate anion

期刊

MENDELEEV COMMUNICATIONS
卷 31, 期 2, 页码 201-203

出版社

ELSEVIER
DOI: 10.1016/j.mencom.2021.03.018

关键词

closo-decaborate; nitrilium derivatives; amino acid esters; glycine; alanine; phenylalanine; amidines

资金

  1. Russian Foundation for Basic Research [20-33-70217]
  2. Council for Grants of the President of the Russian Federation [MK-2403.2019.3]

向作者/读者索取更多资源

The addition of amino acid esters to [2-B10H9-N CMe](-) Bu4N+ salt under mild conditions results in high yields of amidine closo-decaborates. The structure of compound (PPh4)[2-B10H9NH=C(Me)NHCH2COOEt] was determined through single-crystal XRD analysis.
The addition of amino acid esters to [2-B10H9-N CMe](-) Bu4N+ salt under mild conditions affords amidine closo- decaborates in high yields. The structure of compound (PPh4)[2-B10H9NH=C(Me)NHCH2COOEt] was elucidated by single-crystal XRD analysis.

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