期刊
MACROMOLECULES
卷 54, 期 11, 页码 5094-5105出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.1c00365
关键词
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资金
- UK EPSRC
- University of Bath [EP/N022793/1]
- Royal Society [RG/150538, UF/160021, RGF\R1\180036]
- EPSRC [EP/N022793/1] Funding Source: UKRI
In this study, a D-xylose 3,5-anhydrosugar derivative was used as an oxetane co-monomer in the ring-opening copolymerization (ROCOP) with cyclic anhydrides to synthesize a family of seven novel sugar-derived polyesters with up to 100% renewable content. These polyesters are thermally robust and exhibit a broad range of glass-transition temperatures, allowing for further postpolymerization functionalization. The living character of the ROCOP process was also utilized to synthesize block copolymers through sequential co-monomer addition experiments.
A D-xylose 3,5-anhydrosugar derivative has been used as an oxetane co-monomer in the ring-opening copolymerization (ROCOP) with cyclic anhydrides, to form a family of seven novel sugar-derived polyesters, with up to 100% renewable content. ROCOP proceeds with high alternating selectivity to form AB-type copolymers that are thermally robust (T-d,T-onset > 212 degrees C) and exhibit a broad range of glass-transition temperatures (T-g 60-145 degrees C). These polyesters are amenable to further postpolymerization functionalization. The hydroxy group of the sugar moiety can be unveiled, then functionalized further, e.g., phosphorylated. The internal alkene of some of the anhydride moieties can also be subject to thiol-ene reactions. Combining those orthogonal strategies affords AB copolyesters with alternating functional substituents. By exploiting the living character of the ROCOP process, block copolymers have also been synthesized through sequential co-monomer addition experiments.
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