A Stable NanoPAA-ZnO/ZnCl2 Composite with Variable 3D Structured Morphology and Sustained Superhydrophilicity

A ZnO/ZnCl2 composite with stable 3D structural morphologies and long lasting superhydrophilicity was synthesized on the top surface of a nano porous anodic alumina (nanoPAA) substrate. The wettability of a nanoPAA-ZnO/ZnCl2 was systematically characterized and the experimental data indicated that the water contact angle (WCA) of 0 degrees could be achieved as well as maintained over 7 days and still remained at 4.36 degrees after 50 days, and its 3D structural morphology had no clearly observable change during this period. The mechanism for the superhydrophilicity of the composites was interpreted in terms of the inherent hydrophilicity of ZnO/ZnCl2 nanofilm, the three-dimensional structures of wrinkled nanoflakes, the nanogaps between neighbor nanoflakes, the difference of structual morphologies (i.e., size, shape, and upright posture of nanoflakes), and the measured True Volume of voids in the nanocomposite. The structural morphologies were mainly determined by the parameters such as the original concentration of precursor ZnCl2 and the pore diameter of nanoPAA substrate. The study proposes a promising superhydrophilic nanomaterial and a cost-effective synthesis method, which will play a practical role in the fields of biomedical molecular sensors and micro/nanofluidic chips.

Automated summary

A ZnO/ZnCl2 composite with stable 3D structural morphologies and long lasting superhydrophilicity was synthesized on a nanoPAA substrate. The water contact angle of the composite could be maintained at 0 degrees for 7 days and remained low even after 50 days. The superhydrophilicity mechanism was attributed to the properties of the ZnO/ZnCl2 nanofilm, wrinkled nanoflakes, nanogaps, and structural morphologies.