4.6 Article

Oxygen Vacancy-Enhanced Ultrathin Bi2O3-Bi2WO6 Nanosheets' Photocatalytic Performances under Visible Light Irradiation

期刊

LANGMUIR
卷 37, 期 16, 页码 5049-5058

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.1c00576

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资金

  1. Scientific Research Projects for High-Level Talents of Chongqing Technology and Business University [1956032]
  2. youth project of science and technology research program of Chongqing Education Commission of China [KJQN202000824]
  3. Talent planning project of Chongqing [CQYC201903053]
  4. Special General Project of Chongqing Technology Innovation and Application Development [cstcjscx-msxm1374]

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Ultrathin Bi2O3-Bi2WO6 nanosheet composites with abundant oxygen vacancies were successfully synthesized, showing remarkable photocatalytic degradation performance for oxytetracycline compared to pure Bi2WO6 nanosheets. The enhanced photocatalytic activities are attributed to the hetero-junction structure and the introduction of oxygen vacancies by the ultrathin structures.
The oxygen vacancy caused by ultrathin structures would be introduced into the semiconductor photocatalyst to boost its photocatalytic activity. Herein, ultrathin Bi2O3-Bi2WO6 nanosheet composites have been successfully synthesized via a facile hydrothermal method. Compared to pure Bi2WO6 nano-sheets, the Bi2O3-Bi2WO6 nanosheet composites possess abundant oxygen vacancies, which was confirmed by the positron annihilation spectra. The ultrathin Bi2O3-Bi2WO6 nanosheet composites exhibited remarkable photocatalytic degradation performance for oxytetracycline compared with that of pure Bi2WO6 nanosheets. The excellent photocatalytic activities of Bi2O3-Bi2WO6 composites could be attributed to the hetero-junction structure and the oxygen vacancies caused by ultrathin structures.

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