4.6 Article

Shape-Tunable Janus Micromotors via Surfactant-Induced Dewetting

期刊

LANGMUIR
卷 37, 期 16, 页码 4964-4970

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.1c00340

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资金

  1. National Natural Science Foundation of China [12074275, 11704269]
  2. Natural Science Foundation of the Jiangsu Higher Education Institutions of China [20KJA150008, 17KJB140020]
  3. PAPD program of Jiangsu Higher Education Institutions

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The study demonstrates a facile strategy to synthesize Janus micromotors with precisely tunable shapes, providing an important foundation for the creation of intelligent and functional micromachines.
The ability to tune shapes of micromotors is challenging yet crucial for creating intelligent and functional micromachines with shape-dependent dynamics. Here, we demonstrate a facile strategy to synthesize Janus micromotors in large quantity whose shapes can be precisely tuned by a surfactant-induced dewetting strategy. The Janus micromotor is composed of a TiO2 microparticle partially encapsulated within a polysiloxane microsphere. A range of particle shapes, from approximately spherical to snowman, is achieved, and the shape-tunable dynamics of the micromotors are quantified. Our strategy is versatile and can be applicable to other photoactive materials, such as ZnO and Fe2O3 nanoparticles, demonstrating a general approach to synthesize Janus micromotors with controllable shapes. Such shape-tunable micromotors provide colloidal model systems for fundamental research on active matter, as well as building blocks for the fabrication of micromachines.

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