期刊
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY
卷 118, 期 10, 页码 1463-1469出版社
WILEY-BLACKWELL
DOI: 10.1002/ejlt.201500494
关键词
Acrylated soybean oil; Thermosetting resins; Thiol-ene coupling
资金
- National Natural Science Foundation of China [21304079, 51503177]
- Fundamental Research Funds for the Central Universities [20620140066]
- Initial Scientific Research Foundation of Yancheng Institute of Technology [KJC2014001, KJC2014002]
In this study, the bio-based thermosetting resins were synthesized via thiol-ene coupling between acrylated epoxidized soybean oil (AESO) and different functionality of thiols. The structure of the AESO was carefully examined using FT-IR and H-1-NMR measurements. The thermal/mechanical properties of the bio-based thermosetting resins were characterized using DMA, TGA, and tensile test. The DMA results showed that the storage moduli and glass transition temperatures of bio-based thermosetting resins improved with increment of thiols functionality, meanwhile, the tensile strength, Young's modulus, and thermal stability of the AESO-based resins also increased.
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