期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 1, 页码 6-29出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201600983
关键词
Ferrocene; Metallocenes; Electron transfer; Organometallic chemistry; Molecular engineering; Nanostructures; Redox chemistry
资金
- University of Bordeaux
- Centre National de la Recherche Scientifique (CNRS)
- Institut Uiversitaire de France (IUF)
- Ministere de l'Enseignement Superieur et de la Recherche (MESR)
- Chinese Research Council (CRC)
- l'Oreal
The appearance of ferrocene in the middle of the 20th century has revolutionized organometallic chemistry and is now providing applications in areas as varied and sometimes initially unexpected as optical and redox devices, battery and other materials, sensing, catalysis, including asymmetric and en-antioselective catalysis, and medicine. The author presents here a general, although personal, view of ferrocene's chemistry, properties, functions, and applications through a literature survey involving both historical and up-to-date trends and including examples of his group's research in a number of these areas. The review gathers together general features of ferrocene chemistry and representative examples of the salient aspects. Its focus is on ferrocene's basic properties, ferrocene-containing ligands, the ferrocene/ferricinium redox couple, ferrocene mixed-valence and average-valence systems, the ferricinium/ferrocene redox shuttle in catalysis, ligand-exchange reactions, ferrocene-containing polymers, ferrocene-containing structures for cathodic battery and other materials, ferrocenes in supra-molecular ensembles, liquid crystals, and nonlinear optical materials, ferrocene-containing stars and their electrostatic effects, ferrocene-containing dendrons, dendrimers, and nanoparticles (NPs) and their application in redox sensing and catalysis, and ferrocenes in nanomedicine.
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