期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 41, 期 12, 页码 5957-5966出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2021.05.028
关键词
Photovoltaic silicon waste; Recycling; Molybdenum oxide (MoO3); Porous ceramics
资金
- National Natural Science Foundation of China [52064012]
By studying the effects of additive content and sintering temperature on the mullitization reaction of mullite ceramics, it was found that ammonium molybdate tetrahydrate molybdenum can reduce the reaction temperature and potentially be used in the preparation of porous mullite ceramics. The research provides a new idea for the low-cost preparation of porous mullite ceramics with high purity using photovoltaic silicon waste.
In this study, porous mullite ceramics with coral-like structures were fabricated at a low temperature of 900 degrees C by using photovoltaic silicon waste (PSW) as the silicon source directly. The effects of additive content and sintering temperature on the mullitization reaction of green bodies were studied. The results showed that ammonium molybdate tetrahydrate molybdenum (H24Mo7N6O24 center dot 4H(2)O) as an additive could reduce the reaction temperature for mullitization from 1100 degrees C to 900 degrees C. The research on the influence of catalyst on material properties showed that porous mullite ceramics with a flexural strength of 52.83 MPa, a 41.78 % porosity, a sintering expansion rate of 0.49 % and an average pore size of 0.23 mu m could be fabricated by introducing 7.5 % H24Mo7N6O24 center dot 4H(2)O at the sintering temperature of 1000 degrees C. This study develops an environment-friendly recycling method of PSW and provides a new idea for the low-cost preparation of porous mullite ceramics with high purity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据