期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 41, 期 4, 页码 2674-2681出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2020.11.036
关键词
Solid oxide fuel cells (SOFCs); Lanthanum-doped ceria; Ni-Fe bimetal anode; Interfacial reaction; Lanthanum gallate oxide
资金
- Korea Evaluation Institute of Industrial Technology (KEIT) [10063427, 20004693]
- Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea
- National R&D Program through National Research Foundation of Korea (NRF) by Ministry of Science and ICT [2020M3H4A3105824]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10063427] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2020M3H4A3105824] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Solid oxide fuel cells (SOFCs) are gaining attention in the energy sector, yet the choice of electrolyte is crucial. LaGaO3-based electrolyte faces compatibility issues with Ni-based anodes, but introducing an interlayer can enhance efficiency. By optimizing the thickness of La-doped CeO2 interlayer, superior power performance is achieved, offering new possibilities for commercial applications.
Solid oxide fuel cells (SOFCs) have been gaining increased attention in the energy sector. Commonly, yttria-stabilized zirconia is widely employed as commercial electrolyte, however, resulted in drawbacks such as high-temperature operating and low conductivity which negatively affect the durability and efficiency. Thus there are many efforts to find high-ionic conductors. From the point of manufacturing, the major difficulty of LaGaO3-based electrolyte as a high-ionic conductor is its incompatibility with commercial Ni-based anodes during high-temperature processes as well as operating. Several interlayers have been introduced to prevent the reaction between LaGaO3-based electrolyte and Ni-based anode. In this study, we investigate the optimal thickness of the La-doped CeO2 (LDC) interlayer by the screen-printing method using La0.9Sr0.1Ga0.8Mg0.2O3-delta for the commercial electrolyte supported SOFCs. As a result, the superior power performance of 2.2 W.cm(-2) at 1123 K is achieved through the optimized LDC thickness of 20 mu m through not lab-scaled but commercial ceramic manufacturing processing.
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