期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 27, 页码 4349-4352出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201600627
关键词
Metal-organic frameworks; Cluster compounds; Zirconium; Geometry; Topology
资金
- Inorganometallic Catalyst Design Center, an Energy Frontier Research Center
- U. S. Department of Energy, Office of Science, Basic Energy Sciences [DESC0012702]
- MRSEC program of the National Science Foundation at the Materials Research Center of Northwestern University [DMR-1121262]
Gaining control over the assembly of mesoporous Zr-based metal-organic frameworks (MOFs) with modifiable metal nodes remains a challenge. The the topology is intriguing, particularly if considering postsynthetic modification, as it presents large sodalite-like cages surrounded by 12 interconnected 1D channels that allow for efficient diffusion of guest molecules throughout the structure. Herein, we demonstrate the first Zr MOF with the topology, NU-1200, which was synthesized by controlling the geometry of the organic building unit. In addition, by using NU-1200 as a platform, we perform solvent-assisted metal incorporation to form single-site metalated nodes, a process that is characterized by single-crystal X-ray diffraction.
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