期刊
JOURNAL OF POWER SOURCES
卷 490, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2021.229564
关键词
Solid oxide fuel cell; Bi-doped cathode; Oxygen vacancy; First-principles calculation; Electrochemical property
资金
- National Natural Science Foundation of China [22078262, 21576218]
- State Key Laboratory of Chemical Engineering [SKL-CHE-18A02]
- Technology Innovation Talent Serviced Industrial Project of Xi'an Science and Technology Bureau [2020KJRC0114]
In this study, Bi doping was found to be effective in improving the cathode materials for IT-SOFCs by enhancing oxygen vacancy generation energy and promoting electrochemical performance. The Bi3+ doping in LBSCFx cathode materials can accelerate oxygen transportation and increase oxygen reduction reaction sites, leading to significantly reduced polarization resistance and activation energy, ultimately improving the power density of the anode-supported single cells.
To address both challenges of insufficient oxygen vacancies and excessive interface resistance in intermediatetemperature solid oxide fuel cells (IT-SOFCs), in this study, we apply the first-principle density functional study to choose the A-site cation doping M(M = Ca, Ba, Bi) for conventional La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) and find that Bi doping could produce the smallest generation energy of oxygen vacancy. Then novel Bi-doped La0.6-xBixSr0.4Co0.2Fe0.8O3 (LBSCFx, x = 0,0.1,0.2) cathode materials are investigated, revealing Bi3+ doping can promote the electrochemical performance of LBSCFx cathode by the enrichment of oxygen vacancies and the triple-phase boundaries. Attributed to the accelerated oxygen transportation and the increased oxygen reduction reaction sites, the effectiveness of Bi3+ doping LSCF on the reduction of polarization resistant (R-p) and activation energy (E-a) is superior than most of other LSCF doping strategies. The R-p and E-a values of LBSCF0.2 are reduced more than 58% and 27% compared to that of undoped LSCF respectively, and the maximum power density of the anode-supported single cells based on LBSCF0.2 outperforms 1 W.cm(2) at 750 degrees C. Both R-p and power density suggest the effectiveness of Bi doping strategy for developing cathode materials in IT-SOFCs.
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