Deep Blue Circularly Polarized Luminescence Response Behavior of an Achiral Pyrene-Based Emitter Regulated by Chiral Co-assembly Helical Nanofibers

Supramolecular co-assembly provides a brand-new powerful strategy for regulating simple organic molecules into various hierarchical nano- and microstructures as smart functional materials. In particular, chiral supramolecular assemblies with strong fluorescent emission have received extensive attention for their application as circularly polarized luminescence (CPL) emitters. Herein, we synthesized three achiral pyrene derivatives, but only the chiral co-assembly (R/S-NMe2-Py-2) can exhibit the regular and orderly helical nanofiber via pi-pi stacking interaction between chiral N,N'-dimethyl-binaphthyldiamine enantiomers (R/S-NMe2) and the achiral pyrene derivative (Py-2). Interestingly, this kind of 2:1 molar ratio (R/S-NMe2)2-Py-2 co-assembly with a helical nanofiber structure can emit a strong deep blue CPL signal from the achiral pyrene-based emitter, and the dissymmetry factor g(em) value can reach 0.027 (lambda(em) = 423 nm) in the film from spin-coating.

Automated summary

The study synthesized three achiral pyrene derivatives and found that only the chiral co-assembly could form regular and orderly helical nanofibers, emitting a strong deep blue circularly polarized luminescence signal.