期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 412, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2021.113234
关键词
Graphene quantum dots; Fluorescence; Anion detection; Thiosulfate anion; Oxidative compounds
资金
- National Natural Science Foundation of China [21976123]
A novel iodine-mediated nitrogen-doped graphene quantum dots nanoprobe has been developed as a fluorescence "off-on" probe for detecting S2O32-. This nanoprobe has a high sensitivity with a limit of detection down to 93 pM and can also detect other oxidative compounds in addition to S2O32-.
Owing to the huge threat to human health and environment from thiosulfate anion (S2O32- ) widely used in various fields, the development of an effective detection method for S2O32- is urgently desired. Herein, we developed an iodine (I2) mediated nitrogen-doped graphene quantum dots (I2-mediated N-GQDs) as a fluorescence ?off-on? probe for S2O32- by iodimetry reaction oriented strategy. Firstly, I2 interacted with N-GQDs to form non-fluorescent N-GQDs/I2 complex due to the inner filter effect (IFE). In the presence of S2O32-, the iodimetry reaction between I2 and S2O32- disintegrated N-GQDs/I2 complex and re-switched on the quenched photoluminscence of N-GQDs. The I2-mediated N-GQDs nanoprobe with a limit of detection down to 93 pM has been successfully used to sense S2O32- in biological fluids and living cells. Moreover, the I2-mediated N-GQDs/S2O32nanoplatform could further detect oxidative compounds such as hydrogen dioxide, dichromate, permanganate, iron ion (III), copper ion (II), and cerium ion (IV).
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