4.7 Article

Direct Synthesis of ortho-Halogenated Arylphosphonates via a Three-Component Reaction Involving Arynes

期刊

JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 9, 页码 7010-7018

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c00550

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资金

  1. 100 Young Talents Programme of Guangdong University of Technology [220413506]
  2. Science and Technology Planning Project of Guangdong Province [2017A010103044, 2019A050510042]
  3. National Undergraduate Training Program for Innovation and Entrepreneurship [D202011292349499886]

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A three-component reaction involving arynes, trialkyl phosphites, and halides has been achieved under mild reaction conditions, providing a direct synthetic approach to ortho-halogenated arylphosphonates which can be rapidly converted to diversely ortho-functionalized arylphosphorus compounds.
A three-component reaction involving arynes, trialkyl phosphites, and halides has been achieved under mild reaction conditions. This transformation provides a direct synthetic approach to ortho-halogenated arylphosphonates, which could be rapidly converted to diversely ortho-functionalized arylphosphorus compounds.

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