期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 8, 页码 5546-5551出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c00059
关键词
-
资金
- RGC-GRF fund of Hong Kong SAR [14303816]
The successful enlargement of the curved pi-electron periphery of the wizard hat-shaped polycyclic aromatic compound 1 is described in this study. The target structure 2 features a m,m,p,m, m,p, m,m,p-nonaphenylene belt fused to a central tribenzotriquinacene unit, with a multiple regioconvergent Scholl-type dehydrocyclization as the key step in the synthesis. Spectroscopic, structural, and electronic properties of the title compound 2 are also reported.
The successful enlargement of the curved pi-electron periphery of the wizard hat-shaped polycyclic aromatic compound 1 is described. The target structure 2 features an m,m,p,m, m,p, m,m,p-nonaphenylene belt fused to a central tribenzotriquinacene unit. The synthesis involves a multiple regioconvergent Scholl-type dehydrocyclization as the key step. Spectroscopic, structural, and electronic properties of the title compound 2 are reported.
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