Cold sintering of magnetic BaFe12O19 and other ferrites at 300 °C

Densifying ZnFe2O4 and BaFe12O19 at 300 degrees C to values greater than 90% of theoretical is demonstrated via hydroflux-assisted densification (HAD), a derivative of the cold sintering process employing non-aqueous, flux-based mass transport phases to facilitate particle consolidation. Previous attempts to cold sinter these materials with aqueous-based mass transport phases were not as successful with final densities < 90%. Attempts to densify NiFe2O4 and (Ni0.5Zn0.5)Fe2O4 only achieved densities around 80%, indicating an alternative transport phase may be needed to achieve high densities in Ni-containing materials. Magnetic hysteresis measurements of the low-temperature densified BaFe12O19 samples produced magnetic saturation values as high as 93 emu/g and coercive fields as high as 1789 Oe, which are comparable to values reported in the literature for this material produced via other processing techniques. Additional techniques are suggested to further optimize the magnetic properties of BaFe12O19 densified following the HAD approach.

Automated summary

Hydroflux-assisted densification (HAD) demonstrates the efficient densification of ZnFe2O4 and BaFe12O19 at 300 degrees C, achieving densities greater than 90% of theoretical values. Previous attempts using aqueous-based mass transport phases were not as successful, indicating a need for alternative transport phases for achieving high densities in Ni-containing materials. BaFe12O19 samples densified using HAD show promising magnetic properties, with potential for further optimization.