Electrostatic assembly construction of polysaccharide functionalized hybrid membrane for enhanced antimony removal

There is a growing demand for heavy metal removal by membrane technology in real applications. However, few studies were reported concerning antimony (Sb) removal by membrane technology. Herein, a novel thin film nanocomposite (TFN) membrane comprising an alginate (SA) selective layer and a polyether sulfone (PSF) support membrane incorporating chitosan functionalized iron nanocomposite has been firstly developed for Sb removal via electrostatic self-assembly. The support matrix membrane contained iron nanocomposite (denoted as CIM) retained high water flux and porosity, and it reached a maximum removal capacity of 16.5 and 13.6 mg/g for Sb(III) and Sb(V) with nanofiller loading rate of 20% during static experiments, respectively. The coated SA top layer endowed the hybrid membrane (denoted as SA-CIM) to have a lower membrane flux, and have stronger retention abilities for Sb species than that by CIM during dynamic filtration experiments. The SA-CIM membranes also possess tolerable reversibility towards Sb removal. Benefiting from the negatively-charged dense selective layer and high adsorption capacity of the iron nanocomposites, the SA-CIM membranes demonstrated an enhanced removal capacity for Sb species via steric hindrance effect, electrostatic repulsion and adsorption. Our study offers a simple method to remove Sb by a novel polysaccharide functionalized hybrid membrane.

Automated summary

A novel thin film nanocomposite (TFN) membrane comprising an alginate (SA) selective layer and a polyether sulfone (PSF) support membrane incorporating chitosan functionalized iron nanocomposite has been developed for antimony (Sb) removal. The membrane has strong removal capacity and tolerable reversibility towards Sb removal, demonstrating enhanced removal capacity for Sb species.