Sorption of sulfadiazine and flow modeling in an alluvial deposit of a dry riverbed in the Brazilian semiarid

The Brazilian semiarid region is subjected to irregular rainfall, prolonged droughts, and high temperatures, hampering the surface water accumulation. The water access is restricted to the alluvium in the valleys, which are used for cattle and poultry livestock development. These activities trigger the excessive use of veterinary antibiotics. As a consequence, antibiotics reach sediment surfaces and promote deterioration of groundwater quality. This work aims to evaluate the sorption potential of Sulfadiazine (SDZ) and to understand the dynamics of water transfer and solute transport processes in a typical alluvial deposit of the Capibaribe River, in the Agreste of Pernambuco. The sedimentological characterization was performed by Miall's Code, defining four lithofacies (Scm, Scm,b, Gcm,o, Scm,o). Kinetics and isotherms experiments allowed the analyses of SDZ sorption. Kinetics sorption showed an equilibrium tendency after 40 h and was better described by a second-order model, while isotherm sorption data were better fitted by the Freundlich model. According to the particle size distribution curve, Scm had the highest number of fine particles and organic matter, affecting interaction of SDZ in sediments. Consequently, SDZ sorption was slightly higher in this lithofacies. However, overall, SDZ sorption was low, thereby offering a real risk of groundwater contamination. For further investigation the dynamics of water transfer and solute transport in a heterogeneous alluvial deposit were simulated with the HYDRUS-2D. The structural heterogeneity influenced the spatial distribution of water storage under unsaturated conditions and provided the emergence of preferential flows. The solute dynamic follow a similar behavior of the water flow, due to the low retention of SDZ in the soil. Considering a condition near to saturation, the contrast of hydraulic and transport properties influences simultaneously in the processes of water transfer and solute transport.

Automated summary

The Brazilian semiarid region faces challenges of irregular rainfall, prolonged droughts, and high temperatures, limiting surface water accumulation. Livestock activities in the valleys contribute to the excessive use of veterinary antibiotics, leading to groundwater contamination. The study evaluates the sorption potential of Sulfadiazine (SDZ) and the dynamics of water transfer and solute transport processes in an alluvial deposit in the Capibaribe River.