0D/2D CdS/ZnO composite with n-n heterojunction for efficient detection of triethylamine

It is imperative to seek for novel materials with pronounced gas sensing performance towards triethylamine for the sake of human health. Herein, we successfully fabricate an outstanding triethylamine sensor based on CdS/ZnO composite with 0D/2D structure, which are prepared by in-situ growth of CdS quantum dots on ultra-thin ZnO nanosheets. The ratios between the two ingredients are adjusted and their effect is evaluated. The optimal sample exhibits the lowest operating temperature of 200 degrees C, the highest response value of similar to 20 and the fastest response time of 2 s. Besides, it also has the virtues of durable stability, excellent selectivity and superior anti-interference ability. The mechanism behind the aforementioned intriguing performance is investigated by X-ray photoelectron spectroscopy, Kelvin probe and density function theory (DFT) simulation. All the results verify that the enhanced gas sensing properties are derived from splendid 0D/2D structure, n-n heterojunction and large specific surface area. Additionally, this study opens an avenue for designing sensors with 0D/2D structure. (C) 2021 Elsevier Inc. All rights reserved.

Automated summary

A novel CdS/ZnO composite with 0D/2D structure was successfully fabricated as an outstanding triethylamine sensor, exhibiting low operating temperature, high response value, fast response time, durable stability, excellent selectivity, and superior anti-interference ability. The enhanced gas sensing properties were attributed to the splendid 0D/2D structure, n-n heterojunction, and large specific surface area. This study paves the way for designing sensors with 0D/2D structure.