期刊
JOURNAL OF CLEANER PRODUCTION
卷 293, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2021.126140
关键词
Microrecycling; Thermal transformation; Thermal disengagement; Cobalt recovery; Spent lithium ion battery
The study focuses on the recovery of valuable Co metal from spent LIBs using thermal disengagement and selective thermal transformation technique. Through two steps of processing, nearly 99% pure Cu and Al foils were recovered in the first step using a thermal disengagement technique, and approximately 96% pure Co metal was recovered in the second step through thermal transformation at 1400 degrees C.
The significant usage of lithium-ion batteries (LIBs) in compact electronics - and more recently, electric automobiles - will lead to large quantities of scrap batteries and create serious environmental problems. Currently, spent LIBs are not very well recycled, and are predominantly disposed of in landfill. This is risky, due to the presence of hazardous materials in LIBs. However, LIBs contain numerous metallic resources such as copper, aluminium, cobalt and lithium. In particular, recovery of the transition metal cobalt is an attractive proposition as there is a scarcity in the supply of naturally mined cobalt, and there are economical and environmental issues associated with cobalt's mining processes. In this work, a facile process involving thermal disengagement and selective thermal transformation technique was employed for the recovery of valuable Co metal from spent LIBs. LiCoO2 and graphite were thermally disengaged from the cathode and anode of LIBs, and a further selective thermal transformation was carried out. This approach recovered similar to 99% pure Cu and Al foils in the first step - using a thermal disengagement technique without any metal loss. Approximately 96% pure Co metal was recovered in the second step, using thermal transformation to enable carbothermal reduction and transformation at 1400 degrees C. This technology provides a guide for the successful recovery of valuable metal resources and future opportunities for the repurposing of valuable metals from LIBs. (C) 2021 Elsevier Ltd. All rights reserved.
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