4.7 Article

Inverse design of equilibrium cluster fluids applied to a physically informed model

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Summary: By utilizing large deviation theory and principles of stochastic optimal control, optimal forces for targeted self-assembly within nonequilibrium steady-states can be determined to enhance the stability of the target structure. Tunable complexity of specific short-range interactions allows for high yield assembly of colloidal clusters, with shear flow affecting the yield differently based on the rigidity of the clusters. The influence of shear on yield enhancement or suppression is rationalized through a generalized linear response theory, with basic design principles for targeted assembly out of equilibrium uncovered through the study of unique clusters.

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