期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 138, 期 28, 页码 -出版社
WILEY
DOI: 10.1002/app.50677
关键词
cellulose and other wood products; composites; flame retardance; mechanical properties; thermal properties
资金
- National Natural Science Foundation of China [21666005, 22068007]
- Natural Science Foundation of Guangxi Province [2017GXNSFEA198001, 2019GXNSFDA245020]
This study successfully enhanced the thermal stability and mechanical properties of CEMC by using CAO prepared by mechanical activation-assisted solid-phase reaction and surface-modified O-MH, resulting in O-MH/CAO composites with good dispersibility and improved mechanical properties and flame retardancy.
Biomass-based composites with renewability and biodegradability have attracted extensive researches, but their applications are hindered by poor mechanical properties and flame retardancy. Cellulose ester matrix composites (CEMC), a kind of biomass-based composites, were prepared with inorganic crystals as flame retardant and reinforcement. Cellulose acetate oleate (CAO) prepared by mechanical activation-assisted solid-phase reaction was used as thermoplastic matrix. Hydrophobic oleate-magnesium hydroxide (O-MH), which was surface-modified with oleic acid, was embedded into CAO to prepare O-MH/CAO composites by hot pressing. The introduction of oleoyl contributed to favorable thermoplasticity of cellulose ester, resulting in enhanced thermal stability and mechanical properties of CEMC. The uniform dispersion of O-MH in the CAO matrix via metal-organic coordination increased the mechanical properties and flame retardancy of O-MH/CAO composites, ascribing to the toughening effect and combustion inhibition effect induced by O-MH. This study provides a feasible technology for fabricating the CEMC with outstanding thermal stability and mechanical properties.
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