期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 859, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.157879
关键词
One-step growth; Microsphere; NiCoAl-LDH; Supercapacitors
资金
- National Natural Science Foundation of China [21902042, 21871076]
- Natural Science Foundation of Hebei Province [B2020205006]
- Science Foundation of Hebei Normal University [L2019B14]
The one-step fabrication of NiCoAl-LDH microspheres with well-dispersed morphology and high electrochemically active surface area was presented, addressing the issue of aggregation in LDHs nanosheet. The Ni1Co2Al1-LDH microspheres fabricated showed a specific capacitance of 451 F g(-1) at a current density of 5 A g(-1), which is 1.92 times higher than that of conventional lamellar Ni1Co2Al1-LDH, indicating great potential for large-scale manufacture of energy storage materials.
Layered double hydroxides (LDHs) are a class of 2D structure anionic clays with tunable structure, which has high theoretic faradaic capacitance. However, self-aggregation of LDHs nanosheet usually restricts their energy storage performances. Microspheres materials possess high specific surface area and structure stability, which provide a promising method to address the issue of aggregation in LDHs nanosheet. In this work, we present the one-step fabrication of NiCoAl-LDH microspheres with well-dispersed morphology and high electrochemically active surface area. The fabricated Ni1Co2Al1-LDH microspheres present specific capacitance of 451 F g(-1) at current density of 5 A g(-1), which is 1.92 times higher than that of conventional lamellar Ni1Co2Al1-LDH. Based on the Ni1Co2Al1-LDH microspheres, an all-solid-state asymmetric supercapacitor device was fabricated, giving high energy density, power density and long term cycling stability. This one-step growth of NiCoAl-LDH microspheres method has potential applications in large-scale manufacture of energy storage materials. (C) 2020 Elsevier B.V. All rights reserved.
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