4.6 Article

Solubility of Palladium in Alumina-Iron Silicate Melts

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Iron activity measurements and spinel-slag equilibria in alumina- bearing iron silicate slags

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Summary: This study investigated the properties of iron-silicate slags at high alumina concentrations using a high temperature equilibration-quenching method combined with EPMA phase composition data. Experimental measurements of iron activities in molten silicate slags were conducted, and the locations of spinel-liquid slag tie-lines were determined in a specific range of oxygen partial pressure. Comparisons with thermodynamic assessments of the Fe-O-Al2O3 system showed discrepancies between the assessed databases and the experimental data from this study.

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