期刊
IONICS
卷 27, 期 7, 页码 2803-2812出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11581-021-04066-1
关键词
Cu05Ni0 5Co2O4; Spinel; Lithium-ion batteries
A copper-doped lithium-ion battery anode material Cu0.5Ni0.5Co2O4 was successfully synthesized through hydrothermal synthesis and high-temperature calcination, with the assistance of metal-organic framework. The resulting material exhibited excellent electrochemical performance and high specific capacities, thanks to its unique structural features and ability to alleviate volume expansion issues during charge/discharge processes.
A copper-doped lithium-ion battery anode material Cu0.5Ni0.5Co2O4 was obtained through simple hydrothermal synthesis and assisted by high-temperature calcination. Metal-organic framework was introduced into the precursor, and after calcination at 500 degrees C, a porous nano-particle material with the specific surface area of 41.68 m(2) g(-1) was obtained. With the assistance of metal-organic framework, the prepared material can effectively alleviate the volume expansion problem generated during the charge/discharge process and improve the electrochemical performance. More importantly, the Cu0.5Ni0.5Co2O4 electrode material not only maintains good cycle stability but also has a high charge/discharge specific capacity. The material can remain 1347.93 mAh g(-1) after 200 cycles at the current density of 1000 mA g(-1), and has a high discharge specific capacity of 1846.50 mAh g(-1) in the first cycle at the current density of 1000 mA g(-1). Benefit from the structural features, the resultant Cu0.5Ni0.5Co2O4 electrode material exhibits good electrochemical performance with remarkable specific capacities (1411.36-919.76 mAh g(-1)) at various current densities (50-1000 mA g(-1)).
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