4.7 Article

UiO-66-NH2 functionalized cellulose nanofibers embedded in sulfonated polysulfone as proton exchange membrane

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Summary: The SPVdF-HFP/SGO hybrid membrane prepared by incorporating sulfonated graphene oxide (SGO) nanosheets into the sulfonated poly (vinylidene fluoride-co-hexafluoropropylene) (SPVdF-HFP) matrix showed improved water uptake, proton conductivity, reduced methanol uptake, and swelling ratio compared to pristine SPVdF-HFP membrane. The electrostatic interaction between the membrane backbone and SGO skeleton helped to retain lower weight loss during TGA analysis. The hybrid membrane exhibited promising proton conductivity and low methanol permeability, making it a potential candidate for direct methanol fuel cells (DMFCs) applications.

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