期刊
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
卷 183, 期 -, 页码 1402-1409出版社
ELSEVIER
DOI: 10.1016/j.ijbiomac.2021.05.098
关键词
Pickering emulsion; Multilayer emulsion; Chitosan; Sodium alginate; Rheology; Stability
资金
- National Natural Science Foundation of China [31801493]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [17KJB550003]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
This study aimed to enhance the physiochemical stability of chitosan particle stabilized Pickering emulsion by coating with sodium alginate. Different mass ratios of CS and SA were evaluated for their effects on the microstructure, rheology, and stability of the emulsions. The addition of the proper level of SA could increase the stability of the emulsion, but the creaming and flocculation stability were still sensitive to various environmental factors.
The purpose of this study was to further improve the physiochemical stability of the chitosan (CS) particle stabilized Pickering emulsion by coating with sodium alginate (SA). The effect of different mass ratios of CS and SA (1:0.5-1:2) on the microstructure, rheology and the stability of the emulsions were comprehensively evaluated by various methods such as optical microscope, scanning electron microscope, rheometer, and low field nuclear magnetism. The multilayer emulsion with low content of SA (CS:SA = 1:0.5) presented bridging flocculation. If SA concentration was high (CS:SA = 1:1-1:2), the surface of the Pickering emulsion droplets was completely covered by the SA. At this time, multilayer emulsion droplets became stable due to strong electrostatic and/or steric repulsion. Too high SA concentration (CS:GA = 1:2) might also promote the accumulation of moisture. In addition, the CS/SA multilayer emulsion showed higher coalescence stability under different environmental treatments but its creaming stability and flocculation stability were still sensitive to pH (2, 4 and 10), temperature (4 degrees C and 80 degrees C) and ionic strength (300-500 mM). In all, the addition of the proper level SA (CS:GA = 1:1-1:2) could increase the stability of CS particle-stabilized Pickering emulsion. (c) 2021 Elsevier B.V. All rights reserved.
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