期刊
INORGANIC CHEMISTRY
卷 60, 期 9, 页码 6731-6738出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c00553
关键词
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资金
- Western Sydney University (WSU)
- Australian Synchrotron
- Australian Nuclear Science and Technology Organisation
- Australian Research Council [LE170100144, DP130103157, FT140100986, FT140100273]
- Advanced Materials Characterization Facility (AMCF) at WSU.
- Australian Research Council [FT140100986, FT140100273, LE170100144] Funding Source: Australian Research Council
This study investigates the interaction between crystal packing, intermolecular interactions, and the magnetic behavior of SCO materials. The research found that a more separated array of SCO units leads to more extensive spin-transitions, while a tightly arranged lattice environment stabilizes the low-spin state.
A spin-crossover (SCO) active dinuclear Fe(II) triple helicate of the form [Fe2L3](4+) was combined with additional supra-molecular components in order to manipulate the interhelical separation and steric congestion and to study the magneto-structural effects on the ensuing composite materials. A more separated array of SCO units produced more extensive spin-transitions, while a tightly arranged lattice environment stabilized the low-spin state. This study highlights the important interplay between crystal packing, intermolecualr interactions, and the magentic behavior of SCO materials.
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