4.4 Article

A Green's function perspective on the nonequilibrium thermodynamics of open quantum systems strongly coupled to baths Nonequilibrium quantum thermodynamics

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EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS
卷 230, 期 4, 页码 859-866

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SPRINGER HEIDELBERG
DOI: 10.1140/epjs/s11734-021-00067-3

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  1. National Science Foundation [CHE1565939]
  2. University of California San Diego

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In this study, a non-equilibrium Green's function perspective was used to explore thermodynamic formulations for open quantum systems strongly coupled to baths. A scattering approach and a consideration of thermodynamics of a system strongly coupled to its baths were compared. It was argued that the latter approach could lead to a thermodynamic formulation consistent with a dynamic quantum transport description.
We give a nonequilibrium Green's function (NEGF) perspective on thermodynamics formulations for open quantum systems that are strongly coupled to baths. A scattering approach implying thermodynamic consideration of a supersystem (system plus baths) that is weakly coupled to external superbaths is compared with the consideration of thermodynamics of a system that is strongly coupled to its baths. We analyze both approaches from the NEGF perspective and argue that the latter yields a possibility of thermodynamic formulation consistent with a dynamical (quantum transport) description.

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