期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2021, 期 17, 页码 2431-2435出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202100294
关键词
Electrochemical cyclization; Organoselenides; Oxidative cyclization; Seleno isoxazoline; Seleno radicals
An electrochemical oxidative tandem cyclization of unsaturated oximes with diselenides has been developed, providing a general access to seleno isoxazolines containing a quaternary carbon center (35 examples). This novel protocol features mild reaction conditions (metal- and oxidant-free), good functional group tolerance, and promising scalability, with plausible reaction pathways proposed.
Electrochemical oxidative tandem cyclization of unsaturated oximes with diselenides has been developed to provide a general access to seleno isoxazolines containing a quaternary carbon center (35 examples). This novel protocol features with mild reaction conditions (metal- and oxidant-free), good functional group tolerance and promising scalability. Moreover, plausible reaction pathways have been proposed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据